Advanced li-ion batteries

Next-generation lithium-ion (li-ion) batteries are being developed, and varieties are already currently in the marketplace, that are 2-7X the efficiency of current batteries; often while reducing costs. New varieties of advanced li-ion batteries maintain a stable capacity for 20+ years, and can charge in minutes, are rechargable; and have a higher capacity and are more cost-efficient than previous generations. The most common type of high capacity, widely used, advanced batteries being developed today are lithium-ion batteries made in combination with other metals as well as other elements; creating a unique battery technology (like li-ion cobalt oxide, which is frequently used today in portable devices - cell phones, laptops, etc...). [Another metal commonly used in batteries for a wide variety of products and EVs; and often combined with other metals and elements - is nickel. "Nickel (Ni) has long been widely used in batteries, most commonly in nickel cadmium (NiCd) and in the longer-lasting nickel metal hydride (NiMH) rechargeable batteries...".]

A few other examples of advanced li-ion next-gen battery technologies currently in the market (but less widely commercially available than li-ion cobalt varieties; and even less commercially available than lithium-iron-phosphate batteries; which are currently a popular battery solution for some stationary battery applications) include: li-ion siliconli-ion manganese oxide, li-ion sulphur, and li-ion solid state. (Here is a YouTube video on li-iron phosphate batteries, also known as LFP batteries). All of these promising, best-in-class batteries based on advanced li-ion chemistry are more efficient than the products of previous li-ion battery generations; and are also lighter, longer lasting, often still rechargable while also developed to charge quickly; and have a higher energy capacity. These cutting-edge li-ion batteries based on the latest battery chemistries are emerging into the mass marketplace; as they transition from R&D, beta-testing, and demonstration phases. Advanced next-gen li-ion batteries could revolutionize battery technology for smartphones, computers, tablets, electric vehicles, grid storage, commercial/ municipal buildings, RVs, boats, aerospace applications, other industrial applications, and much more.

Widely commercially available advanced li-ion batteries (such as li-ion colbalt oxide, or the promising LFP batteries gaining popularity for home energy storage and EVs) remain the most prominent high capacity batteries widely available in today’s market - for smart phones, laptops, electric vehicles; as well as small-scale (residential/ commercial building), and large-scale (grid, industrial) energy storage. However, sodium-ion batteriesgraphene-based batteries, and zinc-air batteries, represent cheaper, more abundant, more environmentally-friendly material than lithium; that could produce a less expensive battery with possibilities for long-term energy storage and applications for a wide range of products - if R&D in these technologies yields batteries that can be widely commercially marketed.

Lithium-vanadium phosphate batteries are a next-generation battery solution which shows promise; as they can extend the range of electric vehicles (EVs), for example. These batteries potentially have greater power than advanced batteries found in many EVs today, but also greater safety than the batteries found in smartphones and laptops. In addition, recharging lithium-vanadium batteries could be faster than batteries currently used in EVs and computers. Other promising advanced next-gen battery types with varying degrees of research and development, and at different levels of marketability, include flow batteries.

One glaring issue with li-ion batteries is the lack of sustainability in sourcing the critical rare earth metals used in li-ion batteries; especially with cobalt sourced from Congo (cobalt is frequently found in batteries in smartphones, portable computers, and EVs). Cobalt sourced from Congo (which supplies roughly 2/3 of the world's cobalt), and then used in li-ion cobalt oxide batteries (as well as other batteries - for issues such as battery durability and the like) are often product of cobalt mining rife with human rights abuses (child labor, labor for insufficient wages, labor in hazardous, unregulated conditions), unmitigated environmental and social injustices, and other unsustainable practices.

Cobalt is found in many varieties of li-ion batteries, and even nickel-based batteries, and other batteries that use a combination of metals and elements; however there are batteries with no cobalt or other unsustainable rare earth metals (such as those promising battery types mentioned above in this article). There are manufacturers producing li-ion cobalt free batteries, as well as many battery manufacturers committed to using cobalt that is not sourced from Congo; but rather other parts of the world that do not have human rights abuses in cobalt mining.

"Since child and slave labor have been repeatedly reported in cobalt mining, primarily in the artisanal mines of DR Congo, technology companies seeking an ethical supply chain have faced shortages of this raw material and the price of cobalt metal reached a nine-year high in October 2017, more than US$30 a pound, versus US$10 in late 2015. After oversupply, the price dropped to a more normal $15 in 2019. As a reaction to the issues with artisanal cobalt mining in DR Congo a number of cobalt suppliers and their customers have formed the Fair Cobalt Alliance (FCA) which aims to end the use of child labor and to improve the working conditions of cobalt mining and processing in the DR Congo. Members of  another ethical cobalt mining organization, the Responsible Cobalt Initiative, include FairphoneGlencore, and Tesla, Inc. Research is being conducted by the European Union on the possibility to eliminate cobalt requirements in lithium-ion battery production. As of August 2020 battery makers have gradually reduced the cathode cobalt content from 1/3, to 2/10, to currently 1/10, and have also introduced the cobalt free LFP cathode into the battery packs of electric cars such as the Tesla Model 3. In September 2020, Tesla outlined their plans to make their own, cobalt-free battery cells." FROM  -

Flow batteries

Flow batteries, such as vanadium flow and zinc-iron redox flow, have a longer battery life than conventional li-ion batteries. Flow batteries have a battery life of over 20 years, quickly charge and discharge; and easily scale up from under 1 MW to over 10 MW. Vanadium flow batteries represent high capacity energy storage, can be idle when solar and wind aren’t producing, and then discharge instantly. They have the unique ability to charge and discharge simultaneously and to release large amounts of electricity quickly. As they are inexpensive to scale up, vanadium flow batteries represent an opportunity for reliable, affordable large-scale energy storage. At this point, many types of flow batteries are still in the R&D phase due to the expense of manufacturing these batteries; with only limited commercial availability. However, commercial deployment of flow batteries is seen in some areas worldwide today, including some large markets - such as throughout Australia and Asia.

Unlike vanadium flow batteries, which currently represent a great, realistic battery alternative, lithium-air batteries only theoretically represent a great battery alternative. Lithium-air batteries could triple the range of EVs; and could give fully charged EVs the same range as maximum range gasoline cars with a full tank. However, whereas vanadium flow batteries can charge and discharge repetitively with no problem, it has been notoriously difficult to manufacture re-chargable varieties of lithium-air batteries.

New promising batteries are currently being manufactured with everything from li-ion + cobalt, phosphate, manganese, silicon (or combining a bunch of these elements, along with nickel - for lithium nickel manganese cobalt oxides, or NMCs as these batteries are known); as well as batteries based on vanadium, zinc, sodium or even graphene. Advanced R&D is being done on "superconductors", flow batteries, solid-state batteries, and various metal or air-flow type batteries; as well as experimental combinations such as lithium sulfur, lithium-nickel-manganese-cobalt, and lithium-tininate oxide. New advanced next-gen batteries are quickly gaining ground both in terms of R&D, as well as deployment. Advancements in next-gen batteries will help add renewable energy storage to the grid, add charging capacity to our cell phones and laptops, and help extend the range of electric cars to compete with gasoline ones.

The next step in ensuring that future generations of li-ion batteries are actually sustainable solution, is a concerted effort by battery manufacturers to develop batteries with future recycling options built-in the battery design. Here's a snippet from C&EN about the importance of having future recycling requirements in mind as a priority for battery manufacturers:

Lithium-ion batteries have made portable electronics ubiquitous, and they are about to do the same for electric vehicles. That success story is setting the world on track to generate a multimillion-metric-ton heap of used Li-ion batteries that could end up in the trash. The batteries are valuable and recyclable, but because of technical, economic, and other factors, less than 5% are recycled today. The enormousness of the impending spent-battery situation is driving researchers to search for cost-effective, environmentally sustainable strategies for dealing with the vast stockpile of Li-ion batteries looming on the horizon.   FROM -

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